Centering around the lives of pre-teen Hispanic twins named Maya and Miguel Santos and their friends, the program is aimed at promoting multiculturalism and education in general. It is geared to the 5-9 age range. Part of the dialogue in each episode in the English version is in Spanish but only individual words or phrases which are explained in English.
| Title | Air Date | Duration | ||
|---|---|---|---|---|
| Season 1 | Episode 1 | Mala Suerte | 2004-10-11 | 30 min |
| Season 1 | Episode 2 | The Matchmaker | 2004-10-12 | 30 min |
| Season 1 | Episode 3 | When Maya Met Andy | 2004-10-13 | 30 min |
| Season 1 | Episode 4 | The Autograph | 2004-10-14 | 30 min |
| Season 1 | Episode 5 | Rhymes with Gato | 2004-10-15 | 30 min |
| Season 1 | Episode 6 | La Nueva Cocinita | 2004-10-18 | 30 min |
| Season 1 | Episode 7 | The Letter | 2004-10-19 | 30 min |
| Season 1 | Episode 8 | Teacher's Pet | 2004-10-20 | 30 min |
| Season 1 | Episode 9 | La Calavera | 2004-11-02 | 30 min |
| Season 1 | Episode 10 | Politics Unusual | 2004-11-08 | 30 min |
| Season 1 | Episode 11 | Tito's Mexican Vacation | 2004-11-09 | 30 min |
| Season 1 | Episode 12 | Prince Tito | 2004-11-10 | 30 min |
| Season 1 | Episode 13 | The Bully and the Bunny | 2004-11-11 | 30 min |
| Season 1 | Episode 14 | Family Time | 2004-11-12 | 30 min |
| Season 2 | Episode 1 | Career Day | 2005-01-17 | 30 min |
| Season 2 | Episode 2 | Surprise, Surprise | 2005-01-18 | 30 min |
| Season 2 | Episode 3 | An Okri-Dokey Day | 2005-01-19 | 30 min |
| Season 2 | Episode 4 | I've Got to be Mi-guel | 2005-01-20 | 30 min |
| Season 2 | Episode 5 | Chrissy's Big Move | 2005-01-21 | 30 min |
| Season 2 | Episode 6 | Soccer Mom | 2005-02-11 | 30 min |
| Season 2 | Episode 7 | The Adventures of Rabbit-Bird Man | 2005-02-16 | 30 min |
| Season 2 | Episode 8 | Maya and Miguel, Come on Down! | 2005-02-17 | 30 min |
| Season 2 | Episode 9 | The Wrestler Next Door | 2005-02-18 | 30 min |
| Season 2 | Episode 10 | A Little Culture | 2005-05-03 | 30 min |
| Season 2 | Episode 11 | The Bet | 2005-05-04 | 30 min |
| Season 2 | Episode 12 | Team Santos | 2005-05-05 | 30 min |
| Season 2 | Episode 13 | The Cherry Chipper Cupid Sisters | 2005-05-06 | 30 min |
| Season 3 | Episode 1 | The Slump | 2005-07-15 | 30 min |
| Season 3 | Episode 2 | Real Twins | 2005-10-10 | 30 min |
| Season 3 | Episode 3 | Recipe for Disaster | 2005-10-11 | 30 min |
| Season 3 | Episode 4 | Abuela Upmanship | 2005-10-12 | 30 min |
| Season 3 | Episode 5 | The Dogwalkers | 2005-10-13 | 30 min |
| Season 3 | Episode 6 | The Pen-Pal | 2005-10-14 | 30 min |
| Season 3 | Episode 7 | Friends Forever? | 2005-10-21 | 30 min |
| Season 3 | Episode 8 | Fashionistas | 2005-10-28 | 30 min |
| Season 3 | Episode 9 | Maya Quixote and Miguel Panza | 2005-11-04 | 30 min |
| Season 3 | Episode 10 | The Taming of Mr. Shue | 2005-11-11 | 30 min |
| Season 3 | Episode 11 | The Best Thanksgiving Ever | 2005-11-18 | 30 min |
| Season 3 | Episode 12 | Miguel's Wonderful Life | 2005-11-25 | 30 min |
| Season 4 | Episode 1 | Tito's Pet | 2006-01-06 | 30 min |
| Season 4 | Episode 2 | The Video | 2006-01-13 | 30 min |
| Season 4 | Episode 3 | A Star Is Born | 2006-01-20 | 30 min |
| Season 4 | Episode 4 | Paper Girl | 2006-01-27 | 30 min |
| Season 4 | Episode 5 | Cupid | 2006-02-14 | 30 min |
| Season 4 | Episode 6 | Every Day is Earth Day | 2006-04-21 | 30 min |
| Season 4 | Episode 7 | Mother's Day | 2006-05-12 | 30 min |
| Season 4 | Episode 8 | Give Me a Little Sign | 2006-09-25 | 30 min |
| Season 4 | Episode 9 | Decisions, Decisions | 2006-10-03 | 30 min |
| Season 4 | Episode 10 | A Rose is Still A Rose | 2006-10-04 | 30 min |
| Season 4 | Episode 11 | Role Reversal | 2006-10-05 | 30 min |
| Season 4 | Episode 12 | After School | 2006-10-06 | 30 min |
| Season 5 | Episode 1 | Puppy Love | 2007-01-15 | 30 min |
| Season 5 | Episode 2 | The Red Jacket | 2007-01-16 | 30 min |
| Season 5 | Episode 3 | The Battle of the Birthdays | 2007-01-17 | 30 min |
| Season 5 | Episode 4 | Maya the Mascot | 2007-01-18 | 30 min |
| Season 5 | Episode 5 | The Big Idea | 2007-01-19 | 30 min |
| Season 5 | Episode 6 | Paging Dr. Maya | 2007-05-04 | 30 min |
| Season 5 | Episode 7 | Papi Joins the Band | 2007-06-15 | 30 min |
| Season 5 | Episode 8 | The Wedding | 2007-10-01 | 30 min |
| Season 5 | Episode 9 | The Big Fight | 2007-10-02 | 30 min |
| Season 5 | Episode 10 | Crushed | 2007-10-03 | 30 min |
| Season 5 | Episode 11 | Good Luck Paco | 2007-10-04 | 30 min |
| Season 5 | Episode 12 | Say Cheese! | 2007-10-08 | 30 min |
| Season 5 | Episode 13 | A House Divided | 2007-10-09 | 30 min |
| Season 5 | Episode 14 | I Love Maya | 2007-10-10 | 30 min |
| Writing | Deborah Forte | Story Developer |
| Writing | Beth A. Richman | Story Developer |
| Directing | Tony Kluck | Director |
| Sound | Jack Livesey | Music |
| Sound | David Ricard | Music |
| Production | Deborah Forte | Executive Producer |
