Demon King Daimao follows Akuto Sai as the lead character, who on the day he enters Constant Magic Academy, receives a very unexpected future occupation aptitude test result: “Demon King.”
| Title | Air Date | Duration | ||
|---|---|---|---|---|
| Season 1 | Episode 1 | The Demon Lord is Born! | 2010-04-03 | 23 min |
| Season 1 | Episode 2 | The Odd Observer | 2010-04-10 | 23 min |
| Season 1 | Episode 3 | The Upperclassman Who's a Bit Scary | 2010-04-17 | 23 min |
| Season 1 | Episode 4 | The Isolation Cell is Fun? | 2010-04-24 | 23 min |
| Season 1 | Episode 5 | Beware of the Underground Maze | 2010-05-01 | 23 min |
| Season 1 | Episode 6 | Let's Go to School by the Sea | 2010-05-08 | 23 min |
| Season 1 | Episode 7 | The Legendary Hero Appears! | 2010-05-15 | 23 min |
| Season 1 | Episode 8 | Do You Have a Crush? | 2010-05-22 | 23 min |
| Season 1 | Episode 9 | The Marriage Interview Chaos | 2010-05-29 | 23 min |
| Season 1 | Episode 10 | Sai Akuto's Imperial Capital War | 2010-06-05 | 23 min |
| Season 1 | Episode 11 | The Girls' Final Battle | 2010-06-12 | 23 min |
| Season 1 | Episode 12 | The Perfect Ending? | 2010-06-19 | 23 min |
| Production | Masaaki Yokota | Producer |
| Production | Hajime Maruyama | Producer |
| Production | Yuka Sakurai | Producer |
| Camera | Hiroshi Onishi | Director of Photography |
| Directing | Takashi Watanabe | Series Director |
