When marriages fall apart, divorce can turn ugly - even deadly. From blushing brides turned cold-blooded killers to smitten grooms with shocking dark sides, the criminal psychology behind deadly divorces is examined. Guiding viewers through actual stories of love gone wrong are psychotherapist Stacy Kaiser and forensic psychologist Dr. Brian Russell, who analyze each couple to better understand how the marriage turned from flawed to fatal. .
| Title | Air Date | Duration | ||
|---|---|---|---|---|
| Season 1 | Episode 1 | Dead Silence | 2012-11-17 | 60 min |
| Season 1 | Episode 2 | Blood and Wine | 2012-11-24 | 60 min |
| Season 1 | Episode 3 | Secrets of a Dying Man | 2012-12-01 | 60 min |
| Season 1 | Episode 4 | The Last Seduction | 2012-12-08 | 60 min |
| Season 1 | Episode 5 | Death in the Family | 2012-12-15 | 60 min |
| Season 1 | Episode 6 | Lies and Death | 2012-12-22 | 60 min |
| Season 1 | Episode 7 | Your Cheatin' Heart | 2012-12-29 | 60 min |
| Season 1 | Episode 8 | Exquisite Lies | 2013-01-05 | 60 min |
| Season 1 | Episode 9 | The Edge of Love | 2013-01-12 | 60 min |
| Season 1 | Episode 10 | The Pastor, His Wife, Their Son, and His Mistress | 2013-01-19 | 60 min |
| Season 2 | Episode 1 | Half-Baked Alaska | 2013-11-02 | 60 min |
| Season 2 | Episode 2 | In a Lonely Place | 2013-11-09 | 60 min |
| Season 2 | Episode 3 | Romance Reloaded | 2013-11-16 | 60 min |
| Season 2 | Episode 4 | An Inconvenient Marriage | 2013-11-23 | 60 min |
| Season 2 | Episode 5 | Not in Kansas Anymore | 2013-11-30 | 60 min |
| Season 2 | Episode 6 | The Other Side of the Tracks | 2013-12-07 | 60 min |
| Season 2 | Episode 7 | Unholy Trinity | 2013-12-14 | 60 min |
| Season 2 | Episode 8 | Black Pearl | 2013-12-21 | 60 min |
| Season 2 | Episode 9 | Final Notice | 2013-12-28 | 60 min |
| Season 2 | Episode 10 | Decent into Madness | 2014-03-15 | 60 min |
| Season 2 | Episode 11 | Dazed and Deadly | 2014-03-22 | 60 min |
| Season 2 | Episode 12 | Black Widow | 2014-03-29 | 60 min |
| Season 2 | Episode 13 | Burning Love | 2014-04-05 | 60 min |
| Season 3 | Episode 1 | Mid-Life Murder | 2014-11-08 | 60 min |
| Season 3 | Episode 2 | Death of a Salesman | 2014-11-15 | 60 min |
| Season 3 | Episode 3 | Big League Murder | 2014-11-22 | 60 min |
| Season 3 | Episode 4 | Murder by Proxy | 2014-11-29 | 60 min |
| Season 3 | Episode 5 | Death for Dessert | 2014-12-06 | 60 min |
| Season 3 | Episode 6 | Killing Time | 2014-12-13 | 60 min |
| Season 3 | Episode 7 | Hanging by a Thread | 2014-12-20 | 60 min |
| Season 3 | Episode 8 | Hunting Season | 2014-12-27 | 60 min |
| Season 3 | Episode 9 | No Accident | 2015-01-03 | 60 min |
| Season 3 | Episode 10 | The Devil Inside | 2015-01-10 | 60 min |
| Season 3 | Episode 11 | Bloody Matrimony | 2015-01-17 | 60 min |
| Season 3 | Episode 12 | Broken Dreams | 2015-01-24 | 60 min |
| Season 3 | Episode 13 | Death in Vegas | 2015-01-31 | 60 min |
| Season 4 | Episode 1 | You Only Die Once | 2015-10-10 | 60 min |
| Season 4 | Episode 2 | Crazy Love | 2015-10-17 | 60 min |
| Season 4 | Episode 3 | Country Killer | 2015-10-24 | 60 min |
| Season 4 | Episode 4 | Jaws of Death | 2015-10-31 | 60 min |
| Season 4 | Episode 5 | Murder in Store | 2015-11-07 | 60 min |
| Season 4 | Episode 6 | Collision Course | 2015-11-14 | 60 min |
| Season 4 | Episode 7 | Second Chance at Death | 2015-11-21 | 60 min |
| Season 4 | Episode 8 | The Harder They Fall | 2015-11-28 | 60 min |
| Season 4 | Episode 9 | Death Brawl | 2015-12-05 | 60 min |
| Season 4 | Episode 10 | Fall From Grace | 2015-12-12 | 60 min |
| Season 4 | Episode 11 | Sex, Lies and Secret Texts | 2015-12-19 | 60 min |
| Season 4 | Episode 12 | Murder in the Cards | 2015-12-26 | 60 min |
| Season 4 | Episode 13 | At Death's Door | 2016-01-02 | 60 min |
| Season 5 | Episode 1 | Second Chance at Death | 2017-05-13 | 60 min |
| Season 5 | Episode 2 | Love in Flames | 2017-05-20 | 60 min |
| Season 5 | Episode 3 | Blood and Sand | 2017-05-27 | 60 min |
| Season 5 | Episode 4 | Rookie Mistake | 2017-06-03 | 60 min |
| Season 5 | Episode 5 | Recipe for Death | 2017-06-10 | 60 min |
| Season 5 | Episode 6 | Murder in the Marina | 2017-06-17 | 60 min |
| Season 5 | Episode 7 | Hell on Earth | 2017-06-24 | 60 min |
| Season 5 | Episode 8 | Reduced to Ash | 2017-07-01 | 60 min |
| Season 5 | Episode 9 | Deadly Obsession | 2017-07-08 | 60 min |
| Season 5 | Episode 10 | The Ties That Bind | 2017-07-15 | 60 min |
| Season 5 | Episode 11 | A Thin Blue Line | 2017-07-22 | 60 min |
| Season 5 | Episode 12 | Drowning in Tears | 2017-07-29 | 60 min |
| Season 5 | Episode 13 | Death Knows No Borders | 2017-08-12 | 60 min |
| Season 6 | Episode 1 | A Watery Grave | 2018-08-11 | 60 min |
| Season 6 | Episode 2 | Behind Closed Doors | 2018-08-18 | 60 min |
| Season 6 | Episode 3 | Love Gone Bankrupt | 2018-08-25 | 60 min |
| Season 6 | Episode 4 | The Bad Apple | 2018-09-01 | 60 min |
| Season 6 | Episode 5 | Everybody Loves Rick | 2018-09-08 | 60 min |
| Season 6 | Episode 6 | Ambition to Die For | 2018-09-15 | 60 min |
| Season 6 | Episode 7 | Murder, Modesty and the Pastor | 2018-09-22 | 60 min |
| Season 6 | Episode 8 | Curtain Call to Hell | 2018-09-29 | 60 min |
| Season 6 | Episode 9 | Death Outranks Love | 2018-10-06 | 60 min |
| Season 6 | Episode 10 | Living with the Devil | 2018-10-20 | 60 min |
| Season 6 | Episode 11 | Deceitful Secrets | 2018-10-27 | 60 min |
| Season 6 | Episode 12 | Sins of the Heart | 2018-11-03 | 60 min |
| Season 6 | Episode 13 | Bored to Death | 2018-11-10 | 60 min |
| Season 7 | Episode 1 | Murder Behind the Gates | 2020-02-03 | 60 min |
| Season 7 | Episode 2 | Honkytonk Killer | 2020-02-10 | 60 min |
| Season 7 | Episode 3 | Lethal Romance | 2020-02-21 | 60 min |
| Season 7 | Episode 4 | Hell on Wheels | 2020-02-28 | 60 min |
| Season 7 | Episode 5 | Some Like It Dead | 2020-03-06 | 60 min |
| Season 7 | Episode 6 | No Harmony in Polyamory | 2020-03-13 | 60 min |
| Season 7 | Episode 7 | The Unholy Affair | 2020-03-20 | 60 min |
| Season 7 | Episode 8 | My Way or the Dead Way | 2020-03-20 | 60 min |
| Season 7 | Episode 9 | Deadly Isolation | 2020-03-20 | 60 min |
| Season 7 | Episode 10 | Flirting With Murder | 2020-03-27 | 60 min |
| Season 7 | Episode 11 | To Kiss or To Kill | 2020-04-03 | 60 min |
| Season 7 | Episode 12 | Betting on Murder | 2020-04-06 | 60 min |
| Season 7 | Episode 13 | Opposites Can Kill | 2020-04-20 | 60 min |
